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Highly efficient and selective removal of vanadium from tungstate solutions by microbubble floating-extraction

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 581-593 doi: 10.1007/s11705-022-2235-2

摘要： Selective separation of dissolved tungsten and vanadium is of great significance for the utilization of the secondary resources of these elements. In this work, selective removal of vanadium from tungstate solutions via microbubble floating-extraction was systematically investigated. The results indicated that vanadium can be more easily mineralized over tungsten from tungstate solutions using methyl trioctyl ammonium chloride as mineralization reagent under weak alkaline conditions. Owing to the higher bubble and interface mass transfer rates, high-efficiency enrichment and deep separation of vanadium could be achieved easily. Additionally, the deep recovery of tungsten and vanadium from the floated organic phase could be easily realized using a mixed solution of sodium hydroxide and sodium chloride as stripping agents. The separation mechanism mainly included the formation of hydrophobic complexes, their attachment on the surface of rising bubbles, and their mass transfer at the oil–water interface. Under the optimal conditions, the removal efficiency of vanadium reached 98.5% with tungsten loss below 8% after two-stage microbubble floating-extraction. Therefore, the microbubble floating-extraction could be an efficient approach for separating selectively vanadium from tungstate solutions, exhibiting outstanding advantages of high separation efficiency and low consumption of organic solvents.

关键词： tungsten     vanadium     selective separation     reagent mineralization     microbubble floating-extraction    

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Laboratory experiment on using non-floating body to generate electrical energy from water waves

Arunachalam AMARKARTHIK, Srinivasan CHANDRASEKARAN, Karuppan SIVAKUMAR, Harender SINHMAR

《能源前沿（英文）》 2012年 第6卷 第4期   页码 361-365 doi: 10.1007/s11708-012-0210-1

摘要： This paper describes an innovative method of using a non-buoyant body to harness ocean waves. All the point absorbers are buoyant in nature and move up due to buoyancy and come down because of gravity. The point absorbers are designed to move along the waves to make the device efficient. These devices face excessive stress during the rough weather on account of the extreme motion of waves and cause the total device failure. The present study shows that using a non-buoyant body for conventional point absorber principle is much efficient and safer than any other device proposed till today. A small scale wave energy converter with non-buoyant body was designed, fabricated and tested in small scale wave maker. An electrical generator was coupled with the device to generate electrical energy from harnessed waves. The generator was electrically loaded and the generated power was measured. It was found from the experiments that the proposed device showed a significant improvement in electricity generation and safety during extreme conditions. In addition to the electricity generation, the characteristics of the device were also studied by using various wave and device parameters.

关键词： ocean wave energy     point absorbers     heaving body     non-floating object     heave response ratio     electrical energy generation    

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Entity and relation extraction with rule-guided dictionary as domain knowledge

《工程管理前沿（英文）》   页码 610-622 doi: 10.1007/s42524-022-0226-0

摘要： Entity and relation extraction is an indispensable part of domain knowledge graph construction, which can serve relevant knowledge needs in a specific domain, such as providing support for product research, sales, risk control, and domain hotspot analysis. The existing entity and relation extraction methods that depend on pretrained models have shown promising performance on open datasets. However, the performance of these methods degrades when they face domain-specific datasets. Entity extraction models treat characters as basic semantic units while ignoring known character dependency in specific domains. Relation extraction is based on the hypothesis that the relations hidden in sentences are unified, thereby neglecting that relations may be diverse in different entity tuples. To address the problems above, this paper first introduced prior knowledge composed of domain dictionaries to enhance characters’ dependence. Second, domain rules were built to eliminate noise in entity relations and promote potential entity relation extraction. Finally, experiments were designed to verify the effectiveness of our proposed methods. Experimental results on two domains, including laser industry and unmanned ship, showed the superiority of our methods. The F1 value on laser industry entity, unmanned ship entity, laser industry relation, and unmanned ship relation datasets is improved by +1%, +6%, +2%, and +1%, respectively. In addition, the extraction accuracy of entity relation triplet reaches 83% and 76% on laser industry entity pair and unmanned ship entity pair datasets, respectively.

关键词： entity extraction     relation extraction     prior knowledge     domain rule    

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Dynamic performance of submerged floating tunnel with different mooring styles subjected to anchor cable

《结构与土木工程前沿（英文）》 doi: 10.1007/s11709-023-0932-7

摘要： Submerged floating tunnels (SFTs) are novel structures for transportation across long- and deep-strait regions. Owing to severe wave and current excitation as well as the effects of underwater structures and corrosion, the risk of local anchor cable failure is high, which can result in the progressive failure of the entire structure. In this study, experimental and numerical investigations are conducted to analyze the dynamic behavior of an SFT with different mooring styles under local cable failure. A custom-designed cable failure device and the birth-and-death element method are used to simulate cable failure (i.e., progressive failure) via experiments and numerical simulation, respectively. A physical-scale segmental model of an SFT with different mooring styles under anchor cable failure is developed in this study. A segmental and entire-length mathematical model is developed using the ANSYS program to perform the numerical simulation. The results of the segmental numerical and experimental models indicate good agreement. The dynamic response of an SFT with different mooring styles under cable failure is comprehensively investigated by investigating the effects of key parameters (wave period, buoyant weight ratio, and cable failure mechanism). Moreover, the progressive failure of the SFT under cable failure is investigated via a segment model test and a numerical simulation of its entire length. The present study can serve as a reference for the safer designs of the SFT mooring style.

关键词： dynamic behaviors     submerged floating tunnel     cable failure     mooring style     progressive failure    

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Numerical simulation of multi-body floating piers to investigate pontoon stability

Mostafa Shahrabi, Khosrow Bargi

《结构与土木工程前沿（英文）》 2013年 第7卷 第3期   页码 325-331 doi: 10.1007/s11709-013-0209-7

摘要： The objective of this study is to develop a procedure to analyze the motions of a floating pier comprised of several pontoons that are modeled as rigid bodies and connected to each other by flexible and rigid connectors. Recently, the use offloating piers has increased because of their advantages, such as faster and higher-quality construction, seismic force isolation for a full-scale mooring system, low dependence on local soil conditions and tides, ability to relocate or reconfigure the pier modules during the operation period and 75-100 years of repair-free service. A floating pier consists of a pier, access bridge, mooring system and fender system, each of which comes in many variations to suit different usages and construction considerations. The typical loads used in the design of these piers are dead loads, live loads, mooring loads, fender loads and environmental loads induced by wind, currents and waves. For numerical simulation, three types of piers are used: passenger piers, light-cargo piers and semi-heavy-cargo piers. The selected piers consist of several large pontoons joined by pivots and have a pile-based mooring system. These piers are modeled by SAP2000software as two-dimensional frames that are linked together. As the first step, each type of pier is subjected to loading, and its general behavior is assessed. According to this behavior, the major load combinations are described for the design of piers and analyzed to determine the behavior of the modules. Lastly, according to the analysis results and the safe use and stability considerations, such as the maximum draft and longitudinal gradient, the dimensions of each module in each pier type are presented.

关键词： coastal structures     numerical simulation     floating pier     rigid pontoons     stability    

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A method for predicting consolidation settlements of floating column improved clayey subsoil

Jinchun CHAI, Supasit PONGSIVASATHIT,

《结构与土木工程前沿（英文）》 2010年 第4卷 第2期   页码 241-251 doi: 10.1007/s11709-010-0024-3

摘要： A method of predicting the consolidation settlement-time curve of floating soil-cement column on improved soft clayey subsoil has been proposed. The degree of the consolidation (()) of the system is calculated by the double soil-layer consolidation theory, and the methods for evaluating the equivalent hydraulic conductivity () and the coefficient of volume compressibility () of the part of the column improved layer have been proposed. The effectiveness of the method was verified by comparing predictions with the results of finite element analysis (FEA) using a unit cell model. The consolidation settlement (()) can be calculated by the method of treating a part of the column improved layer as an unimproved layer and using the corresponding average () value. By comparing the predicted results with the measurements of laboratory model tests and three case histories in Fukuoka, Japan, the effectiveness of the proposed methods has been verified. It is suggested that the method can be used for designing the soft clayey subsoil improvement using floating soil-cement columns.

关键词： cement depth mixing     ground improvement     consolidation     settlement    

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Role of biologic components in a novel floating-bed combining

Hailiang SONG, Xianning LI, Wei LI, Xiwu LU

《环境科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 215-225 doi: 10.1007/s11783-013-0587-z

摘要： A novel floating-bed incorporated with water spinach ( ), Asiatic clam ( ), and carrier media supported biofilm was developed for eutrophic water purification. The contributions of each biologic component to the removals of total nitrogen (TN), total phosphorus (TP) and Chl.a were examined. The nutrient removals due to the direct uptake by either water spinach or Asiatic clam were less than 10%, suggesting a negligible role of biologic assimilation and leaving the biofilm as the indispensable biologic component in the floating-bed. Chl.a was reduced mainly by Asiatic clams via filter-feeding. Meanwhile, the digestion and excretion of Asiatic clams benefited the proliferation of nitrifying and denitrifying bacteria, resulting in the improvement of TN removal. In summary, the synergetic effects of water spinach, Asiatic clams and biofilms would promote the eutrophic water treatment performance of floating-bed in comparison with the conventional floating-bed with vegetation as the single biologic component.

关键词： floating-bed     Corbicula fluminea     biofilm carrier     eutrophication    

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Resistance of large caisson in floating transport considering the influence of air

Junjie ZHENG, Zongzhe LI, Dongan ZHAO, Qiang MA, Rongjun ZHANG,

《结构与土木工程前沿（英文）》 2010年 第4卷 第3期   页码 331-338 doi: 10.1007/s11709-010-0085-3

摘要： This paper deals with the floating resistance of super large caisson by numerical simulation, and the influence of air resistance on the caisson, which is often ignored by previous researchers, is considered. The floating caisson of Taizhou Highway Bridge’s middle tower pier is investigated, and the software package FLUENT is used to simulate the floating process of large-scale rounded rectangular steel caisson. This simulation adopts the volume of fluid (VOF) model with water-air two-phase flow, which can take both the hydraulic resistance and air resistance into account. Subsequently, the analyses on hydraulic resistance and air resistance under different working conditions, such as different flow velocities and different draughts of water are performed, and the results are compared with those calculated by related empirical formula. The comparison shows that the air resistance takes up notable portion in the total resistance on the floating caisson, and the effect of air resistance on the safety of caisson should be paid sufficient attention to rather than be ignored.

关键词： large-scale caisson     numerical simulation     hydraulic resistance     air resistance    

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High-precision gyro-stabilized control of a gear-driven platform with a floating gear tension device

《机械工程前沿（英文）》 2021年 第16卷 第3期   页码 487-503 doi: 10.1007/s11465-021-0635-5

摘要： This study presents an improved compound control algorithm that substantially enhances the anti-disturbance performance of a gear-drive gyro-stabilized platform with a floating gear tension device. The tension device can provide a self-adjustable preload to eliminate the gap in the meshing process. However, the weaker gear support stiffness and more complex meshing friction are also induced by the tension device, which deteriorates the control accuracy and the ability to keep the aim point of the optical sensors isolated from the platform motion. The modeling and compensation of the induced complex nonlinearities are technically challenging, especially when base motion exists. The aim of this research is to cope with the unmeasured disturbances as well as the uncertainties caused by the base lateral motion. First, the structural properties of the gear transmission and the friction-generating mechanism are analyzed, which classify the disturbances into two categories: Time-invariant and time-varying parts. Then, a proportional-integral controller is designed to eliminate the steady-state error caused by the time-invariant disturbance. A proportional multiple-integral-based state augmented Kalman filter is proposed to estimate and compensate for the time-varying disturbance that can be approximated as a polynomial function. The effectiveness of the proposed compound algorithm is demonstrated by comparative experiments on a gear-drive pointing system with a floating gear tension device, which shows a maximum 76% improvement in stabilization precision.

关键词： inertially stabilized platform     floating gear tension device     nonlinear friction     disturbance compensation     proportional multiple-integral observer    

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Trajectory planning and base attitude restoration of dual-arm free-floating space robot by enhanced bidirectional

Zongwu XIE1 , Xiaoyu ZHAO1 , Zainan JIANG1 , Haitao YANG2 , Chongyang LI1

《机械工程前沿（英文）》 2022年 第17卷 第1期 doi: 10.1007/s11465-021-0658-y

摘要： When free-floating space robots perform space tasks, the satellite base attitude is disturbed by the dynamic coupling. The disturbance of the base orientation may affect the communication between the space robot and the control center on earth. In this paper, the enhanced bidirectional approach is proposed to plan the manipulator trajectory and eliminate the final base attitude variation. A novel acceleration level state equation for the nonholonomic problem is proposed, and a new intermediate variable-based Lyapunov function is derived and solved for smooth joint trajectory and restorable base trajectories. In the method, the state equation is first proposed for dual-arm robots with and without end constraints, and the system stability is analyzed to obtain the system input. The input modification further increases the system stability and simplifies the calculation complexity. Simulations are carried out in the end, and the proposed method is validated in minimizing final base attitude change and trajectory smoothness. Moreover, the minute internal force during the coordinated operation and the considerable computing efficiency increases the feasibility of the method during space tasks.

关键词： free-floating space robot     dual arm     coordinated operation     base attitude restoration     bidirectional approach    

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An extraction- assay system: Evaluation on flavonols in plant resistance to Pb and Cd by supercriticalextraction- gas chromatography

Xu Zhang, Huanhuan Yang, Xinlei Wang, Wen Song, Zhaojie Cui

《环境科学与工程前沿（英文）》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1059-2

摘要：

SFE-GC system is established for flavonols assessment.

Optimal parameters of SFE-GC are evaluated and determined.

Quercetin and kaempferol are detected in plant under heavy metal stress.

Gene expression analysis shows consistent regularity with content of flavonols.

ROS level is applied for elaborating the plant resistance status.

关键词： Flavonols     Heavy metal     Supercritical carbon dioxide extraction (SFE)     GC     Plant resistance    

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Floating forest: A novel breakwater-windbreak structure against wind and wave hazards

《结构与土木工程前沿（英文）》 2021年 第15卷 第5期   页码 1111-1127 doi: 10.1007/s11709-021-0757-1

摘要： A novel floating breakwater-windbreak structure (floating forest) has been designed for the protection of vulnerable coastal areas from extreme wind and wave loadings during storm conditions. The modular arch-shaped concrete structure is positioned perpendicularly to the direction of the prevailing wave and wind. The structure below the water surface acts as a porous breakwater with wave scattering capability. An array of tubular columns on the sloping deck of the breakwater act as an artificial forest-type windbreak. A feasibility study involving hydrodynamic and aerodynamic analyses has been performed, focusing on its capability in reducing wave heights and wind speeds in the lee side. The study shows that the proposed 1 km long floating forest is able to shelter a lee area that stretches up to 600 m, with 40%–60% wave energy reduction and 10%–80% peak wind speed reduction.

关键词： floating structure     breakwater     windbreak     hydrodynamic     CFD    

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Feature extraction from slice data for reverse engineering

ZHANG Yingjie, LU Shangning

《机械工程前沿（英文）》 2007年 第2卷 第1期   页码 25-31 doi: 10.1007/s11465-007-0004-z

摘要： A new approach to feature extraction for slice data points is presented. The reconstruction of objects is performed as follows. First, all contours in each slice are extracted by contour tracing algorithms. Then the data points on the contours are analyzed, and the curve segments of the contours are divided into three categories: straight lines, conic curves and B-spline curves. The curve fitting methods are applied for each curve segment to remove the unwanted points with pre-determined tolerance. Finally, the features, which consist of the object and connection relations among them, are founded by matching the corresponding contours in adjacent slices, and 3D models are reconstructed based on the features. The proposed approach has been implemented in OpenGL, and the feasibility of the proposed method has been verified by several cases.

关键词： feasibility     corresponding     B-spline     pre-determined tolerance     extraction    

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A microextraction approach for rapid extraction and separation of Mn(II) and Co(II) using saponified

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 963-972 doi: 10.1007/s11705-021-2081-7

摘要： In this paper, we proposed a microextraction approach for the extraction and separation of Mn(II) and Co(II) from sulfate solution simulating leachate of spent lithium-ion battery cathode materials using saponified di-(2-ethylhexyl)phosphoric acid system. The effects of the following operational variables were investigated: equilibrium pH, tri-n-butyl phosphate concentration, saponification rate, two-phase ratio and residence time. The results showcased that the microextractor can reach the extraction equilibrium within 20 s, thereby greatly reducing necessary extraction time comparing to that of conventional processes. The volumetric mass transfer coefficient showed 8–21 times larger than that of batch device. With the help of microextractor, 95% of Mn(II) was extracted with a single theoretical stage at a chosen two-phase ratio of 3:1, and the separation factor βMn/Co was as large as 65.5. In the subsequent stripping step, more than 99% of manganese from loaded phase was easily stripped under optimal conditions. The microextraction approach greatly enhances the mass transfer while enabling a continuous and controllable extraction process within a simple structure design. When extracting spent electrode material with microextractors, the comprehensive recovery of mangenese can reach 96%. The microextraction approach has a good applicability in the spent lithium-ion battery cathode materials recycling at both bench and industrial scales.

关键词： extraction equilibrium     mass transfer coefficient     microextraction     multicomponent extraction     di-(2-ethylhexyl)phosphoric acid    

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Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination

Qingyun CHANG, Jingwen ZHANG, Xin DU, Jingjun MA, Jingci LI,

《环境科学与工程前沿（英文）》 2010年 第4卷 第2期   页码 187-195 doi: 10.1007/s11783-010-0030-7

摘要： A simple and efficient liquid-phase microextraction (LPME) technique was developed using ultrasound-assisted emulsification solidified floating organic drop microextraction (USAE-SFODME) combined with flame atomic absorption spectrometry, for the extraction and determination of trace copper in water samples. 1-(2-Pyridylazo)-2-naphthol (PAN) was used as chelating agent. Microextraction efficiency factors (including extraction solvent type, extraction volume, time, temperature, and pH), the amount of the chelating agent, and salt effect were investigated and optimized. Under the optimum extraction conditions, figures of merit of the proposed method were evaluated. The calibration graph was linear in the range of 20–600 g·L with a detection limit of 0.76 g·L. The relative standard deviation (R.S.D) for ten replicate measurements of 20 and 400 g·L of copper was 3.83% and 2.65%, respectively. Finally, the proposed method was applied to tap water, river water, and sea water, and accuracy was assessed through the analysis of certified reference water or recovery experiments.

关键词： ultrasound-assisted emulsification     solidified floating organic drop microextraction     flame atomic absorption spectrometry     preconcentration     copper    

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标题 作者 时间 类型 操作

Highly efficient and selective removal of vanadium from tungstate solutions by microbubble floating-extraction

期刊论文

Laboratory experiment on using non-floating body to generate electrical energy from water waves

Arunachalam AMARKARTHIK, Srinivasan CHANDRASEKARAN, Karuppan SIVAKUMAR, Harender SINHMAR

期刊论文

Entity and relation extraction with rule-guided dictionary as domain knowledge

期刊论文

Dynamic performance of submerged floating tunnel with different mooring styles subjected to anchor cable

期刊论文

Numerical simulation of multi-body floating piers to investigate pontoon stability

Mostafa Shahrabi, Khosrow Bargi

期刊论文

A method for predicting consolidation settlements of floating column improved clayey subsoil

Jinchun CHAI, Supasit PONGSIVASATHIT,

期刊论文

Role of biologic components in a novel floating-bed combining

Hailiang SONG, Xianning LI, Wei LI, Xiwu LU

期刊论文

Resistance of large caisson in floating transport considering the influence of air

Junjie ZHENG, Zongzhe LI, Dongan ZHAO, Qiang MA, Rongjun ZHANG,

期刊论文

High-precision gyro-stabilized control of a gear-driven platform with a floating gear tension device

期刊论文

Trajectory planning and base attitude restoration of dual-arm free-floating space robot by enhanced bidirectional

Zongwu XIE1 , Xiaoyu ZHAO1 , Zainan JIANG1 , Haitao YANG2 , Chongyang LI1

期刊论文

An extraction- assay system: Evaluation on flavonols in plant resistance to Pb and Cd by supercriticalextraction- gas chromatography

Xu Zhang, Huanhuan Yang, Xinlei Wang, Wen Song, Zhaojie Cui

期刊论文

Floating forest: A novel breakwater-windbreak structure against wind and wave hazards

期刊论文

Feature extraction from slice data for reverse engineering

ZHANG Yingjie, LU Shangning

期刊论文

A microextraction approach for rapid extraction and separation of Mn(II) and Co(II) using saponified

期刊论文

Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination

Qingyun CHANG, Jingwen ZHANG, Xin DU, Jingjun MA, Jingci LI,

期刊论文